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- 1The Dog-Gone Affair (Pilot)September 13, 1966
- 2The Prisoner of Zalamar AffairSeptember 20, 1966
- 3The Mother Muffin AffairSeptember 27, 1966 ยท 4.5
- 4The Mata Hari AffairOctober 4, 1966
- 5The Montori Device AffairOctober 11, 1966
- 6The Horns-of-the-Dilemma AffairOctober 18, 1966
- 7The Danish Blue AffairOctober 25, 1966
- 8The Garden of Evil AffairNovember 1, 1966
- 9The Atlantis AffairNovember 15, 1966
- 10The Paradise Lost AffairNovember 22, 1966
- 11The Lethal Eagle AffairNovember 29, 1966
- 12The Romany Lie AffairDecember 6, 1966
- 13The Little John Doe AffairDecember 13, 1966
- 14The Jewels of Topango AffairDecember 20, 1966
- 15The Faustus AffairDecember 27, 1966
- 16The U.F.O. AffairJanuary 3, 1967
- 17The Moulin Ruse AffairJanuary 17, 1967
- 18The Catacomb and Dogma AffairJanuary 24, 1967
- 19The Drublegratz AffairJanuary 31, 1967
- 20The Fountain of Youth AffairFebruary 7, 1967
- 21The Carpathian Caper AffairFebruary 14, 1967
- 22The Furnace Flats AffairFebruary 21, 1967
- 23The Low Blue C AffairFebruary 28, 1967
- 24The Petit Prix AffairMarch 7, 1967
- 25The Phi Beta Killer AffairMarch 14, 1967
- 26The Double-O-Nothing AffairMarch 21, 1967
- 27The U.N.C.L.E. Samurai AffairMarch 28, 1967
- 28The High and the Deadly AffairApril 4, 1967
- 29The Kooky Spook AffairApril 11, 1967